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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS
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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS

Published on: June 20, 2014

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在Fe-Oxo-Mediated C-H功能化反应中,直接动力学轨迹展示了动态匹配和非统计学基数对中间体

Jyothish Joy1, Daniel H Ess1

  • 1Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602, United States.

Journal of the American Chemical Society
|March 23, 2023
PubMed
概括

非血氧复合物通过原子转移 (HAT) 与C-H键发生反应. 新的动态揭示了反应选择性是由动态效应驱动的,而不仅仅是中间体,为C-H功能提供了一个新的模型.

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