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Updated: Aug 2, 2025

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在纳米双上将二氧化碳高选择性电化学降解为甲

Jin Cai1, Qing Zhao2, Wei-You Hsu3

  • 1Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095-1595, United States.

Journal of the American Chemical Society
|April 18, 2023
PubMed
概括

这项研究引入了一种具有双边界的新型铜电催化剂,用于有效减少二氧化碳. 催化剂对甲生产具有很高的选择性,为可持续的燃料生产提供了有希望的途径.

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相关概念视频

Acid Halides to Ketones: Gilman Reagent01:14

Acid Halides to Ketones: Gilman Reagent

Lithium dialkyl cuprate, also known as Gilman reagents, selectively reduces acid halides to ketones. The acid chloride is treated with Gilman reagent at −78 °C in the presence of ether solution to produce a ketone in good yield.
As shown below, the mechanism proceeds in two steps. First, one of the alkyl groups of the reagent acts as a nucleophile and attacks the acyl carbon of the acid chloride to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen...
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