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Luis León-Alcaide1, Rasmus S Christensen2, David A Keen3

  • 1Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/ Catedrático José Beltrán, 2, 46980 Paterna, Spain.

概括

研究人员开发了MUV-24,这是第一个可化的铁基化物化物框架 (ZIF). 这种新材料在冷却后转化为金属有机框架玻璃, 呈现出增强的机械性能并保持其结构完整性.

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Ionic Crystal Structures02:42

Ionic Crystal Structures

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Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Transition Zone01:28

Transition Zone

The transition zone in concrete is a critical area where aggregate meets cement paste, marked by a distinct porosity and weakness compared to the surrounding material. The adhesion around the aggregates is primarily due to Van Der Waals forces. The voids within this zone influence its robustness; initially, it is less durable than the surrounding bulk mortar due to larger voids. Initially, when concrete is compacted, a higher water-cement ratio near the aggregates leads to the formation of...
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Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
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