在有孔空间隔离的金属有机框架中同时控制灵活性和刚性
Yuchen Xiao1, Yichong Chen1, Wei Wang1
1Department of Chemistry, University of California, Riverside, California 92521, United States.
Journal of the American Chemical Society
|May 10, 2023
概括
研究人员开发了高度连接的柔性金属有机框架 (MOF),称为CPM-220. 这些材料具有可调整的刚性,在恶劣条件下保持结晶性,对气体分离有希望.
科学领域:
- 材料科学
- 化学学
- 纳米技术
背景情况:
- 灵活的金属有机框架 (MOF) 通常仅限于低连接的框架 (<9).
- 在保持灵活性和刚性的同时实现高连接性是MOF设计的一个重大挑战.
研究的目的:
- 开发一个创建高度连接的MOF的平台, 具有集成的灵活性和刚性.
- 研究这些新材料的结构和吸收特性.
主要方法:
- 利用基于孔隙空间分区的PACS (分区ACS网) 的全平台方法来设计和合成MOF.
- 通过X射线衍射和吸附研究来描述材料的结构完整性,灵活性和刚性.
主要成果:
- 成功合成了一系列高连接的MOF (CPM-220),具有特殊的灵活性和可调整的刚性.
- 尽管有显著的轴向收缩 (约30%) 和苛刻的处理,但X射线质量的单晶性被证明是保留的.
- 观察到高/环选择性和C3H6和C3H8的异常吸附等温.
结论:
- 该平台可以创建具有前所未有的特性的高级MOF.
- CPM-220材料在气体分离中提供了有前途的应用,特别是C2H2/CO2.
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