水的宏观和微观放松动态之间的相关性:证据表明有两种液体形式
Nguyen Q Vinh1,2, Luan C Doan1,2, Ngoc L H Hoang1
1Department of Physics and Center for Soft Matter and Biological Physics, Virginia Tech, Blacksburg, Virginia 24061, USA.
The Journal of chemical physics
|May 26, 2023
概括
研究人员使用太赫兹光谱学研究水的动力学,揭示了两种不同的液体形式. 这提供了对水的洞察力.
科学领域:
- 物理化学 物理化学
- 生物物理学的生物物理.
背景情况:
- 水的独特特性对生命至关重要,源于其结网络和分子动力学.
- 研究水的动态是具有挑战性的,因为它强烈吸收太赫兹辐射.
研究的目的:
- 描述水的太赫兹介电反应在广泛的温度范围内.
- 探索水中的分子运动和放松过程.
- 调查水的不同液态形式的潜在存在.
主要方法:
- 使用高精度的太赫兹光谱仪测量水的介电反应.
- 覆盖了从超冷液体到接近沸点的温度范围.
主要成果:
- 确定了动态放松过程,包括集体定向,单分子旋转和键重组.
- 建立了宏观和微观放松动态之间的直接相关性.
- 提供了两种不同的液态水形式,具有不同的过渡温度和激活能量的证据.
结论:
- 这项研究提供了一种直接的方法来测试水动态的微观计算模型.
- 这些发现增强了我们对水的复杂行为及其对生命的影响的理解.
更多相关视频
相关概念视频
Atomic Nuclei: Types of Nuclear Relaxation
337
Nuclear relaxation restores the equilibrium population imbalance and can occur via spin–lattice or spin–spin mechanisms, which are first-order exponential decay processes.
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers...
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers...
337
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
350
Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the...
350
Pressure Variation in a Fluid at Rest
305
In a fluid at rest, the pressure at any point beneath the fluid surface depends solely on the depth, not on the container's shape or size. This principle, known as hydrostatic pressure, arises because, in stationary fluids, there is no acceleration, meaning the forces within the fluid balance out. Only vertical forces, caused by the weight of the fluid above, contribute to pressure changes with depth.
When measuring pressure at two different levels within the fluid, the difference in...
When measuring pressure at two different levels within the fluid, the difference in...
305


