作为活性生物合体成分的奇托桑对糖水凝中染料扩散的影响
1Faculty of Chemistry, Brno University of Technology, Purkyňova 464/118, 612 00 Brno, Czech Republic.
Gels (Basel, Switzerland)
|May 26, 2023
概括
与纯亚加相比,富含奇托的亚加水凝具有显著更高的染料吸附能力和减少的染料扩散. 由于静电相互作用,染料扩散在基托桑修饰的水凝中是pH依赖的.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 糖水凝被广泛使用,但与带电分子的相互作用有限.
- 奇托是一种天然的多糖,具有能够与各种物质相互作用的功能组.
- 用奇托修改水凝可以提高它们的特性,用于特定的应用,例如去除染料.
研究的目的:
- 调查基托桑丰富对 agarose水凝中染料的扩散和吸附的影响.
- 量化染料扩散系数和吸附能力的变化.
- 探索pH对染料-水凝相互作用的影响.
主要方法:
- 用奇托丰富的阿加罗斯水凝的制备.
- 确定直接蓝色1,星红色F3B和反应蓝色49的有效扩散系数.
- 吸附实验用于测量染料吸收.
- 在不同pH值 (3, 7, 11) 进行的扩散研究.
主要成果:
- 与纯亚加相比,酸盐丰富的水凝的吸附能力是纯亚加的几倍.
- 染料的有效扩散系数在添加奇托后显著下降.
- 桑丰富的水凝中的扩散系数随着pH值的增加而增加.
- 在有色和透明的水凝区域之间观察到明显的边界和度跳跃,特别是在较低的pH值.
结论:
- 基托桑丰富增强了阿加水凝的染料吸收能力.
- 素的加入通过改变水凝结构和引入相互作用来减少染料扩散.
- 基托桑和染料之间的静电相互作用是pH值依赖的,影响扩散,导致明显的视觉模式.
相关概念视频
DNA Agarose Gel Electrophoresis
97.5K
Agarose gel electrophoresis is a laboratory technique commonly used to separate DNA fragments by size. However, it can also be used to isolate and purify DNA fragments using a gel extraction protocol.
Gel extraction follows five major steps: running gel electrophoresis to separate fragments, isolating the individual bands, extracting DNA from those bands, and removing the dye and salts from the extracted mixture to obtain pure DNA.
In cloning experiments, both the insert and vector DNA...
Gel extraction follows five major steps: running gel electrophoresis to separate fragments, isolating the individual bands, extracting DNA from those bands, and removing the dye and salts from the extracted mixture to obtain pure DNA.
In cloning experiments, both the insert and vector DNA...
97.5K
Colloids
17.6K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.6K
Colloidal precipitates
634
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
634
Coagulation
341
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
341
Colloids and Suspensions
1.9K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
1.9K


