聚合物接种的纳米粒子具有可变的接种密度,用于高能量密度的聚合物纳米复合材料介电电容器
Bhausaheb V Tawade1, Maninderjeet Singh2, Ikeoluwa E Apata1
1Department of Chemistry, Howard University, Washington, D.C. 20059, United States.
JACS Au
|May 26, 2023
概括
聚合物移植纳米粒子 (PGNP) 介电材料提供了增强的能量储存. 低接种密度的PGNP表现出优越的导电性和介电强度,为先进电容器实现高能量密度.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 纳米技术纳米技术
- 介电材料 介电材料
背景情况:
- 先进的储能系统需要高能量密度介电电容.
- 纳米复合材料介电材料结合了无机和聚合物的特性.
- 聚合物移植纳米粒子 (PGNP) 系统提供了对材料属性的协同控制.
研究的目的:
- 为了合成核心外的酸多聚甲酸 (BaTiO3-PMMA) PGNP.
- 为了研究接种密度和分子质量对介电性质的影响.
- 开发可调节的高能量密度储能设备.
主要方法:
- 使用表面启动原子转移聚合 (SI-ATRP) 合成BaTiO3-PMMA PGNP.
- 种类繁多的接种密度 (0.303到0.929链/nm2) 和高分子质量 (97700到130000g/mol).
- 介电性质的表征,包括电容性和介电强度.
主要成果:
- 低接种密度和高分子质量的PGNP表现出更高的导电性和介电强度.
- 达到大约5.2 J/cm3的能量密度,比纳米复合材料混合物高出一个数量级.
- 观察到更高的能量密度,归因于星型聚合物形状和增强的分解.
结论:
- 低接种密度的PGNP显示出高能量密度介电电容器的巨大潜力.
- 这些发现为开发可调节的基于PGNP的储能设备提供了指导原则.
- 开发的PGNP适用于商业介电电容应用.
更多相关视频
05:33Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
Published on: August 12, 2013
21.7K
08:59Synthesizing a Gel Polymer Electrolyte for Supercapacitors, Assembling a Supercapacitor Using a Coin Cell, and Measuring Gel Electrolyte Performance
Published on: November 30, 2022
4.5K
相关概念视频
Capacitor With A Dielectric
4.0K
Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
4.0K
Dielectric Polarization in a Capacitor
4.8K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
4.8K
