磁热性质与磁性交换相互作用在Gd中的相关性54Fe36B10-Si 无形合金
Huiyan Zhang1,2,3, Jia Tan3, Xue Zhang3
1Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials, Anhui University of Technology, Ministry of Education, Ma'anshan 243002, China.
Materials (Basel, Switzerland)
|May 27, 2023
概括
将 (Si) 添加到加多-铁- (Gd-Fe-B) 合金中,可以提高热稳定性和磁热性质. 然而,过度的含量会由于原子相互作用的改变而降低这些磁性特性.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 磁力学 磁力学 是一种
背景情况:
- 基于加多的合金对磁性制冷应用具有前景.
- 了解 (B) 和 (Si) 等合金元素的作用对于优化磁热性质至关重要.
- 旋是一种常见的技术,用于生产无形磁性材料.
研究的目的:
- 研究Gd54Fe36B10-xSix无形合金中替代的影响.
- 分析磁交换相互作用及其与磁热性质的相关性.
- 为了确定最佳的含量,以提高热稳定性和磁热性能.
主要方法:
- 使用融技术制造无形丝带.
- 使用分子场理论和两个子网格模型分析磁交换相互作用.
- 导出交换常数 (JGdGd,JGdFe,JFeFe) 来理解原子相互作用.
主要成果:
- 适当的Si替代改善了热稳定性,最大的磁变化,并扩大了磁热效应.
- 过度的Si含量导致了分裂的结晶峰值,改变了磁过渡,降低了磁热性质.
- 发现Fe-Si原子相互作用比Fe-B更强,诱导组合波动并影响磁性行为.
结论:
- 含量显著影响Gd-Fe-B无形合金的磁热性质.
- 优化Si替代可以提高磁性制冷性能.
- 观察到的变化归因于交换相互作用和材料异质性的变化.
更多相关视频
相关概念视频
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Paramagnetism
2.6K
Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
2.6K
Diamagnetism
2.5K
Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
2.5K
Magnetic Susceptibility and Permeability
1.2K
In linear magnetic materials, like paramagnets and diamagnets, magnetization is proportional to the magnetic field intensity. The constant of proportionality, a dimensionless number, is called magnetic susceptibility. The value of the susceptibility depends on the type of material.
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
1.2K
Colors and Magnetism
12.0K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
12.0K
Magnetostatic Boundary Conditions
1.0K
An electric field suffers a discontinuity at a surface charge. Similarly, a magnetic field is discontinuous at a surface current. The perpendicular component of a magnetic field is continuous across the interface of two magnetic mediums. In contrast, its parallel component, perpendicular to the current, is discontinuous by the amount equal to the product of the vacuum permeability and the surface current. Like the scalar potential in electrostatics, the vector potential is also continuous...
1.0K


