液体金属的同位体热膨胀性和同位体热压缩性
Yuri N Starodubtsev1,2, Vladimir S Tsepelev1
1Research Center for Physics of Metal Liquids, Ural Federal University, Yekaterinburg 620002, Russia.
Materials (Basel, Switzerland)
|May 27, 2023
概括
这项研究揭示了液体金属凝聚能与点的热力学特性之间的关系. 新的方程将凝聚性能量与热膨胀率和点联系起来,在各种金属类型中得到验证.
科学领域:
- 热力学是一种热力学.
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 了解液体金属的凝聚能量对于预测它们的行为至关重要.
- 热力学系数为原子间相互作用提供了洞察力.
研究的目的:
- 研究液体金属在点上的体积热力学系数和原子间键能之间的关系.
- 根据可测量的热力学性质来导出凝聚能量的预测方程.
主要方法:
- 用维度分析来建立理论关系.
- 用于验证各种金属组 (,性土,稀土,过渡) 的实验数据.
主要成果:
- 凝聚能被发现与点 (T) 与热膨胀率 (α) 的比率的平方根成正比.
- 热膨胀率 (α) 显示独立于原子大小和振动振幅.
- 大量压缩能力 (β) 和内部压力 (p) 与原子振动振幅呈指数关系.
- 热压 (p) 随着原子大小的增加而下降.
- 对fcc和hcp金属和金属观察到最高的确定系数.
结论:
- 确定了液体金属的凝聚能和热力学系数之间的定量关系.
- 提供了一种方法来计算电子和原子振动在点对格鲁尼森参数的贡献.
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