释放反应式POSS作为EPDM/PP基础TPV的辅助剂的潜在使用
Nazlı Yazıcı Çakır1, Özgenur İnan2, Merve Ergün1
1Department of Chemical Engineering, Kocaeli University, 41001 Kocaeli, Turkey.
Polymers
|May 27, 2023
概括
乙烯基功能化的多面体寡聚丝素 (OV-POSS) 纳米颗粒增强乙烯二烯单体/聚烯 (EPDM/PP) 热塑性化物 (TPV). 这项研究表明,OV-POSS通过在动态化过程中集成到EPDM/PP网络中来改善机械性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 热塑性化物 (TPV) 通过动态化结合了弹性和热塑性质.
- 乙烯二烯单体/聚乙烯 (EPDM/PP) TPV被广泛使用,但在过氧化物交叉连接过程中可能会出现副作用.
- 传统的凝聚剂用于减轻这些副作用,但正在寻找新的解决方案.
研究的目的:
- 调查乙烯功能化的多面体寡合体丝素 (OV-POSS) 纳米颗粒作为EPDM/PPTPV生产中的新型辅助剂的有效性.
- 为了比较OV-POSS与三酸 (TAC) 等传统凝聚剂的性能.
- 评估OV-POSS含量和EPDM/PP比对TPV特性的影响.
主要方法:
- 在EPDM/PP混合物中,过氧化物启动的动态化.
- 纳入OV-POSS纳米颗粒作为辅助剂.
- 使用OV-POSS的TPV与传统凝聚剂的比较分析.
- 合成TPV的机械性能测试.
主要成果:
- 与OV-POSS合成的TPV与传统凝聚剂相比表现出增强的机械性能.
- 在动态火山化过程中,OV-POSS积极参与了三维EPDM/PP网络结构的形成.
- 该研究探讨了不同的POSS内容和EPDM/PP比率,以优化TPV性能.
结论:
- 在EPDM/PPTPV中,OV-POSS作为有效的辅助剂,提高了材料性能.
- 将OV-POSS集成到聚合物网络中是观察到的机械增强的关键.
- 这项研究提出了一种新的方法,用于开发具有优越性质的先进TPV材料.
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