双功能Z方案TiO2 @MoS2 @NC 多元体结构用于光驱超快的离子存储
Jinhang Li1, Yuqiang Zhang1, Yiyang Mao2
1Key Laboratory of In-Fiber Integrated Optics (Ministry of Education), College of Physics and Optoelectronic Engineering, Harbin Engineering University, Harbin, 150001, China.
Angewandte Chemie (International ed. in English)
|May 27, 2023
概括
研究人员使用N-doped碳涂层的MoS2纳米板和TiO2纳米管开发了新的双功能光电极. 这些材料有效地在光离子电池中收集和存储太阳能,显示出高容量和仅光充电能力.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 电化学 电化学 电化学
背景情况:
- 高效地收集和储存太阳能对于利用可再生能源至关重要.
- 双功能光电极为集成太阳能捕获和储存提供了一个有希望的方法.
- 开发具有增强光电性质的先进材料是一个持续的挑战.
研究的目的:
- 设计和合成用于双功能光电极的新型多重异构结构.
- 为了研究这些光电极在光离子电池 (photo-SIB) 中的性能.
- 探索能量储存设备仅用光充电的潜力.
主要方法:
- 制造多重异构结构,包括在管状TiO2.2上涂上N-doped碳涂层的MoS2纳米板.
- 在黑暗和可见光条件下组装和电化学测试照片SIB设备.
- 使用实验和理论方法分析电荷转移和载体分离的表征.
主要成果:
- 设计的多重异构结构在2.0 A g-1.1可见光下在照片SIB中实现了399.3 mAh g-1的容量.
- 观察到0.71%的高光转换效率.
- 照片SIB表现出了显著的仅光充电能力,容量为231.4 mAhg-1.1.
结论:
- 多重异构结构显著提高了电荷转移动力学和结构稳定性.
- 设计的接口促进了光激发载体的有效分离.
- 这项工作提出了开发双功能光电极的新策略,以有效利用太阳能.
相关概念视频
Formation of Complex Ions
23.8K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.8K
Thermal and Photochemical Electrocyclic Reactions: Overview
2.4K
Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
2.4K
Ionic Crystal Structures
14.5K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.5K
The Z-Scheme of Electron Transport in Photosynthesis
10.3K
The light reactions of photosynthesis assume a linear flow of electrons from water to NADP+. During this process, light energy drives the splitting of water molecules to produce oxygen. However, oxidation of water molecules is a thermodynamically unfavorable reaction and requires a strong oxidizing agent. This is accomplished by the first product of light reactions: oxidized P680 (or P680+), the most powerful oxidizing agent known in biology. The oxidized P680 that acquires an electron from the...
10.3K
Ionic Bonding and Electron Transfer
41.8K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
41.8K


