活性SiO2-Pt亚努斯合物在稀释的聚乙烯氧化物溶液中的动力学
Harishwar Raman1, Sneham Das2, Hrithik Sharma1
1Department of Chemical Engineering, Indian Institute of Technology Kanpur, Kanpur208016, India.
ACS physical chemistry Au
|May 30, 2023
概括
聚合物添加剂显著阻碍了自动运动的Janus合体 (JCs) 的运动,使它们的运动从平滑过渡到停止. 这一发现对于理解复杂生物环境中的微游泳动态至关重要.
科学领域:
- 合体和表面科学科学
- 软物质物理学 软物质物理学
- 生物物理学的生物物理.
背景情况:
- 简氏合体 (JCs) 是模仿生物生物体的合成微游泳器.
- 它们的自主运动对药物/货物交付应用有希望.
- 了解复杂介质 (如聚合物溶液) 中的 JC 动态是必不可少的.
研究的目的:
- 研究聚乙烯氧化物 (PEO) 对SiO2-Pt JCs的自我扩散运动的影响.
- 描述JC动态中的转变与聚合物度的增加.
- 提出一种机制,用于观察到活动运动的阻碍.
主要方法:
- 使用过氧化为燃料的SiO2-Pt Janus合物.
- 在稀释的聚乙烯氧化物溶液中研究了JC运动.
- 分析了不同聚合物度的运动模式 (弹道,旋转) 的变化.
主要成果:
- 聚乙烯氧化物) 抑制了JCs的弹道运动和旋转波动.
- 观察到从平滑到动的过渡,子跳跃,随着PEO度的增加而停止运动.
- 粘度仍然是牛顿式,并且可以忽略不计的增加,表明非粘性阻力机制.
结论:
- 不同类型的聚合物-JC相互作用可能会增加局部阻力,阻碍活跃运动.
- 这项研究揭示了一种影响聚合物溶液中微游泳器动态的新奇机制.
- 这些发现对于在生物和复杂的流体环境中设计有效的微型设备至关重要.
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