在化物暴露后,和硬化水泥中的扩散潜力
Elke Ziehensack1, Sylvia Keßler2, Ueli Angst3
1Centre for Building Materials, Technical University of Munich, Franz-Langinger-Straße 10, 81245 Munich, Germany.
概括
水泥糊中的扩散潜力可能会影响腐蚀研究. 这项研究澄清了它们的行为,发现了由于高pH值的小潜力,但指出pH值差异可能会干扰测量.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 土木工程 土木工程是指土木工程.
背景情况:
- 扩散潜力显著影响钢筋混凝土的腐蚀评估,需要对基于水泥的材料有更深入的了解.
- 硬质材料的永久选择性会影响离子运输和由此产生的扩散潜力.
研究的目的:
- 为了研究水泥糊的选择性行为及其对在强加的NaCl梯度下扩散潜力的影响.
- 分析离子度概况,并将其与测量的扩散潜力相关联.
主要方法:
- 使用扩散电池研究硬化普通波特兰水泥 (OPC) 和高炉水泥 (BFC) 糊.
- 采用激光剥离感应合等离子体质谱法 (LA-ICP-MS) 进行Cl,Na,K和Ca度概况的高分辨率 (100微米) 测定.
- 测量了各种水-水泥比率 (0.30-0.70) 的水泥糊样本的扩散潜力.
主要成果:
- 高炉水泥 (BFC) 糊表现出明显的Cl-和Na+流动性,这表明了永久选择性.
- 尽管具有永久选择性,但由于高孔溶液pH值 (13-14),在所有面料中测量的扩散潜力很小 (-6到+3mV),由于高孔溶液pH值 (13-14).
- 通过扩散细胞设置的pH差异被发现会干扰精确的扩散潜力测量.
结论:
- 水泥材料中的高pH水平减轻了扩散潜力,但pH梯度可能会引入测量错误.
- 精确测量水泥中的扩散潜力需要仔细考虑和控制pH值差异.
- 了解离子流动性和永久选择性对于可靠的混凝土结构腐蚀监测至关重要.
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