高温无金属分子铁电,具有较大的自发极化
Yan-Xin Zhao1, Kai-Ge Gao2, Zi-Shuo Yao1
1Key Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, People's Republic of China.
Inorganic chemistry
|May 31, 2023
概括
两个新的无金属分子铁电, (HMTAH) Cl和 (HMTAH) Br,表现出高工作温度和大自发偏振. 这些材料为铁电技术带来了有前途的进步.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 晶体学 晶体学是指结晶学.
背景情况:
- 在过去的二十年中,许多分子铁电已经开发出来.
- 具有高工作温度和大自发偏振的无金属分子铁电仍然很稀缺.
研究的目的:
- 为了合成和描述新的无金属分子铁电.
- 调查单质子六甲基氨酸 (HMTA) 衍生物在铁电应用中的潜力.
主要方法:
- 单质子六甲基铁胺 (HMTA) 衍生物的结晶, (HMTAH) Cl 和 (HMTAH) Br.
- 结构分析以确定极点组 (3m).
- 铁电性质的表征使用第二生成,铁电歇斯底里循环和火电电流测量.
主要成果:
- 合成的化合物 (HMTAH) Cl和 (HMTAH) Br具有铁电特性.
- 这些材料表现出分别为8.3和8.1μC cm-2的大型自发偏振.
- 记录了高工作温度: (HMTAH) Cl 的 390 K 和 (HMTAH) Br 的 435 K.
结论:
- HMTAH+电离子的半球几何结构使其能够进行180度的重定向,从而产生铁电.
- (HMTAH) Cl和 (HMTAH) Br代表了无金属铁电材料的重大进展.
- 这些发现为设计高性能分子铁电材料开辟了新的途径.
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