在光催化中改善的演化,用Ni-固的g-C3N4
Penghui Bai1, Chenjie Wang1, Juan Xie1
1School of New Energy and Materials, Southwest Petroleum University (SWPU), Chengdu 610500, People's Republic of China.
Nanotechnology
|May 31, 2023
概括
我们开发了一种简单的方法来制造Ni-修饰的聚合物碳化物 (g-C3N4) 纳米片. 这些新型催化剂表现出增强的光催化生产,显著超过纯g-C3N4.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 光催化作用的光催化
背景情况:
- 聚合碳化物 (g-C3N4) 是光催化的一个有前途的材料.
- 提高g-C3N4对进化的效率仍然是一个挑战.
研究的目的:
- 通过一种简单的湿化学方法合成Ni-修饰的g-C3N4纳米片.
- 为了研究Ni/g-C3N4.4的结构和电子特性.
- 评估Ni/g-C3N4对进化的光催化性能.
主要方法:
- 易于湿化学合成Ni-修饰的g-C3N4纳米片.
- 用于结构分析的X射线吸收细结构 (XAFS) 光谱.
- 在可见光照射下进行光催化进化实验.
主要成果:
- 形成一个独特的Ni-N结构,Ni原子固定在g-C3N4空洞中.
- 通过Ni固对g-C3N4电子结构的修改,增强催化活性.
- /g-C3N4催化剂在光催化 H2 进化过程中表现出强大的性能.
- /CN-45催化剂的H2产量达到8482.14μmol·g-1·h-1,明显高于纯g-C3N4.
结论:
- 简单的合成方法产生了Ni-修饰的g-C3N4,具有独特的Ni-N相互作用.
- 的定有效地增强了g-C3N4.4的光催化演化活性.
- 开发的Ni/g-C3N4催化剂代表了可见光驱动光催化学的重大进步.
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