化诱导的分解增加了固体酸的氧化还原活性及其对土壤生物地质化学的影响
Caiqin Wang1, Shuting Tang2, Hangzhe Chen2
1College of Environment, Zhejiang University of Technology, Hangzhou 310014, China; Key Laboratory of Microbial Technology for Industrial Pollution Control of Zhejiang Province, Hangzhou 310014, China; Mizuda Group Co. LTD, Huzhou 313000, China.
The Science of the total environment
|May 31, 2023
概括
化导致固体酸 (HA固体) 分解,增加它们的氧化还原活性. 这影响了土壤碳循环和性环境中的污染物降解.
科学领域:
- 土壤科学 土壤科学
- 环境化学环境化学
- 生物地质化学生物地质化学
背景情况:
- 固体酸 (HA固体) 对土壤生态系统服务至关重要,特别是在性土壤中.
- 它们的功能与它们的化学结构和电化学特性密切相关.
研究的目的:
- 研究化如何影响HA固体的形态学,功能组和氧化还原活性.
- 讨论这些变化对土壤生物地质化学的影响.
主要方法:
- 原子力显微镜 (AFM) 用于粒子形态和偏移成像.
- 测量泽塔电位以评估表面电荷.
- AFM-红外光谱 (AFM-IR) 和光强度用于分析功能组.
- 导电性和电子交换能力 (EEC) 测量以确定氧化还原活性.
主要成果:
- 化诱导HA固体分解,在pH10.0下将粒子大小降低到200nm.
- 超分子聚合放松,暴露更多的氧化还原活性功能组,增加对降解的易感性.
- 导电率下降了42.86%,而EEC从pH值5.0增加了45.30%,从pH值5.0增加到10.0,表明氧化还原活性增强.
结论:
- 化通过粒子分解和功能组暴露增强HA固体的氧化还原活性.
- 增加的氧化还原活性可以加速有机污染物的降解,但也会增加性土壤中的有机碳损失.
- 这项研究阐明了性土壤碳动力学和生物地化学过程中HA固体的作用.
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