在低温和真空条件下通过虹矩阵升华形成的晶体水冰的结构
Reo Sato1, So Taniguchi1, Naoki Numadate1
1Department of Basic Science and Komaba Institute for Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505, Japan.
The Journal of chemical physics
|June 1, 2023
概括
科学家们使用Ne升华在13K的温度下制造了立方冰Ic. 这种新的方法产生了高度结晶的冰Ic,克服了以前低温形成的限制.
科学领域:
- 材料科学 材料科学 材料科学
- 低温物理 低温物理
- 晶体学 晶体学是指结晶学.
背景情况:
- 冰I存在于六角形 (Ih),立方形 (Ic) 和堆叠无序 (Isd) 的形式.
- 无形水在60K以下是转移稳定的,这通常会阻止冰的形成.
- 以前的立方体冰形成方法需要更高的温度 (78K以上).
研究的目的:
- 研究一种在超低温度下形成晶体冰的新方法.
- 通过Ne升华形成的冰的结构和堆叠障碍的特征.
- 在特定条件下,探索从无形水中形成冰结构的形成路径.
主要方法:
- 使用一种新开发的低温反射高能电子衍射 (RHEED) 技术.
- 由Ne从13K的固体H2O/Ne (1:1000比) 矩阵中升华而形成的冰.
- 分析了冰结构和堆叠障碍作为矩阵厚度的函数.
主要成果:
- 成功形成了晶体冰Ic,在13K的立方堆叠序列.
- 与蒸汽沉积的冰相比,观察到明显减少的堆叠障碍 Isd.
- 证明,无形水最初形成,随后形成立方堆叠序列.
- 堆叠障碍的程度低于低温RHEED的检测极限.
结论:
- 在低温 (13K) 和低压下制造立方冰Ic的新有效途径是Ne矩阵化.
- 这种方法提供了一种形成高结晶冰的方法,克服了以前技术的局限性.
- 这些发现为在超稳定条件下冰的形成机制提供了新的见解.
更多相关视频
相关概念视频
Crystal Growth: Principles of Crystallization
2.2K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
2.2K
States of Water
51.0K
Water exists in any one of the three classical states: solid (ice), liquid (water), and gas (steam or water vapor). The state of water depends on i) the intermolecular forces that draw molecules together and ii) the kinetic energy that leads to movements that pull them apart.
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
51.0K
Molecular and Ionic Solids
17.3K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.3K
Ionic Crystal Structures
14.5K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.5K
Recrystallization: Solid–Solution Equilibria
1.1K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
1.1K
Cryo-electron Microscopy
3.4K
Conventional electron microscopy (EM) involves dehydration, fixation, and staining of biological samples, which distorts the native state of biological molecules and results in several artifacts. Also, the high-energy electron beam damages the sample and makes it difficult to obtain high-resolution images. These issues can be addressed using cryo-EM, which uses frozen samples and gentler electron beams. The technique was developed by Jacques Dubochet, Joachim Frank, and Richard Henderson, for...
3.4K


