D3+通过光离子化分子D2-D2二元体的形成
Yonghao Mi1, Enliang Wang2,3, Zack Dube4
1Joint Attosecond Science Laboratory, National Research Council and University of Ottawa, Ottawa, Ontario, Canada. ymi@uottawa.ca.
Nature chemistry
|June 1, 2023
概括
二元体 (D2-D2) 的光离子化主要形成三阳离子 (D3+). 这一发现是通过五秒激光脉冲观察到的,这可能解释了星际分子云中H3+的高丰度.
科学领域:
- 物理化学 物理化学
- 化学物理 化学物理
- 天体化学是天体化学.
背景情况:
- 分子二元 (H2-H2) 对于理解化学相互作用至关重要.
- 三酸 (H3+) 是星际有机分子和恒星形成的关键中间体.
- 在分子云中H3+的高丰度尚未完全理解.
研究的目的:
- 为了研究二元体 (D2-D2) 主导的光电离路.
- 探索解释星际H3+丰富性的潜在机制.
主要方法:
- 利用近红外,秒激光脉冲进行光电离.
- 采用巧合动量成像来检测弹出的粒子.
- 进行了ab initio分子动力学模拟以提供理论支持.
主要成果:
- 观察到的主要道是从D2-D2中喷射出一个原子,发生在5秒内.
- 这一过程主要形成三阳离子 (D3+).
- 模拟准确地重现了实验结果.
结论:
- 从超冷的D2-D2气体中确定了D3+形成的新途径.
- 这种机制为星际环境中H3+的高丰度提供了潜在的解释.
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