刷修改弹性体的污染阻力
Travis S Laws1, William K Ledford2, Kayla Kurtz3
1Department of Chemical and Biomolecular Engineering, University of Tennessee, Knoxville, Tennessee 37996, United States.
ACS applied materials & interfaces
|June 2, 2023
概括
使用瓶修饰弹性体的环保防涂层显示出有前途. 一种配合聚合物添加剂与西洛和化单体证明对大多数海洋污染物有效,为生物杀菌剂提供了可持续的替代品.
科学领域:
- 材料科学 材料科学 材料科学
- 海洋生物学 海洋生物学
- 表面化学 表面化学
背景情况:
- 传统的防涂层依赖于生物制剂,这些生物制剂会损害海洋生态系统.
- 越来越需要环保涂料,以防止通过物理相互作用造成海洋污染.
研究的目的:
- 开发和评估基于瓶修饰弹性体的环保防涂层.
- 为了研究表面性能和防腐阻力之间的关系.
主要方法:
- 用抗污染的侧链合成瓶刷添加剂.
- 添加剂通过混合和共价附着将其纳入商业弹性体中.
- 使用飞行时间二次离子质谱 (TOF-SIMS) 和原子力显微镜 (AFM) 进行表面表征.
主要成果:
- 在八种测试材料中,污染性能差异很大 (硬污染物覆盖率:1.47.2%;软污染物覆盖率:29.164.0%).
- 表面成分是由瓶化学和加载决定的,是影响污染的主要因素,而不是表面粗度.
- 一种带有西洛和化单体的瓶共聚合物证明了广泛的抗污染效果.
结论:
- 瓶修饰弹性体为开发无毒防涂料提供了一个可行的平台.
- 表面化学对于控制污染至关重要,特定的共聚合物配方表现出卓越的性能.
- 进一步开发可能会导致有效的,对环境无害的解决方案,以防止海洋生物污染.
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