扭曲纤维素纳米纤维的有限元素模型之间的强有吸引力的相互作用通过扭曲的交织
1Department of Industrial Chemistry, Faculty of Engineering, Tokyo University of Science 6-3-1 Niijuku, Katsushika-ku Tokyo 125-8585 Japan uetani@ci.tus.ac.jp.
RSC advances
|June 2, 2023
概括
了解扭曲纤维素纳米纤维 (CNFs) 之间的吸引力是材料性质的关键. 最佳的对齐和性管理,特别是扭曲交织,最大限度地提高了CNF的吸引力和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 生物材料是一种生物材料.
背景情况:
- 纤维素纳米纤维 (CNFs) 呈现出对更高阶结构性质至关重要的内在扭曲.
- 控制纳米纤维之间的相互作用对于纸张和织品等应用至关重要.
研究的目的:
- 分析内在扭曲的纤维素纳米纤维 (CNFs) 之间的吸引力.
- 为了研究相对导向和奇拉性对CNF相互作用的影响.
主要方法:
- 使用有限元模型模拟扭曲的CNF形态.
- 在不同的平行和对角接近配置下分析了吸引力.
- 研究了CNF两层脑膜层之间的相互作用.
主要成果:
- 当平行CNF模型的扭转在90°旋转时被网时观察到的最大吸引力.
- 最稳定的结构是由于右手CNF扭曲而在3.2°对角接近角度实现的.
- 阴性层之间最大的吸引力发生在 -2°左侧积累度.
结论:
- 扭曲的CNF之间的吸引力高度依赖于它们的相对对齐和奇拉性.
- 状物管理,特别是扭曲交织,对于控制CNF聚合物的特性至关重要.
- 研究结果为设计具有量身定制物理特征的先进纤维素基材料提供了洞察力.
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