灵活的MNP/TPU/PPy核心外膜的剂工程用于可控制的电磁干扰屏蔽
Wenxuan Zhao1, Biao Zhao2, Zhengchen Wu1
1Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Academy for Engineering & Technology, Fudan University, Shanghai 200438, P. R. China.
ACS applied materials & interfaces
|June 2, 2023
概括
这项研究优化了电导聚合物复合材料的电磁干扰 (EMI) 屏蔽. 用p-toluenesulfonate添加的聚烯醇显示出出色的EMI屏蔽效率和机械灵活性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 纳米技术 纳米技术
背景情况:
- 本质导电聚合物 (ICP) 由于导电性和灵活性,对电磁干扰 (EMI) 屏蔽有希望.
- 兴奋剂过程极大地影响了ICP导电性和EMI屏蔽效率 (SE).
- 为增强EMI屏蔽优化剂选择仍然是一个挑战.
研究的目的:
- 探索可控制导电性,EMI SE和导电性聚合物复合材料中的机械性能.
- 为了确定在EMI屏蔽应用中最适合用于聚烯 (PPy) 的剂.
- 开发先进,灵活和智能的EMI屏蔽材料.
主要方法:
- 在热塑性聚氨框架上使用聚烯 (PPy) 作为导电涂层制造复合膜.
- 纳入磁纳米粒子用于增强磁性损失.
- 对PPy的各种兴奋剂进行系统的研究,重点关注导电性,EMI SE和机械性能.
主要成果:
- 由p-toluenesulfonate添加PPy的复合膜表现出优异的性能.
- 在X频段实现了平均SE26.3dB,在0.2mm厚度的特定SE为1563.17dBcm2g-1
- 证明了出色的机械性能 (16.0 MPa拉伸应力,538.0%延长) 和耐用性 (92.3%的SE保留在10,000个曲周期后).
结论:
- 在EMI屏蔽应用中,p-toluenesulfonate被确定为PPy的最佳剂.
- 开发的复合材料为需要有效的EMI屏蔽的先进,灵活和智能电子设备提供了一个有前途的替代方案.
- 强调了剂工程在调整EMI屏蔽导电聚合物的材料特性方面的重要性.
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