((II) 作为能量材料中的燃料原子
Alexandra M Bacon1, Warren Tomlinson2, Joseph P Hooper2
1Department of Chemistry, Temple University, 1901 N. 13th St., Philadelphia, Pennsylvania 19122, United States.
Inorganic chemistry
|June 2, 2023
概括
测量了包括在内的四种金属复合物的燃烧能量. (II) 三 (pyrazolyl) 酸盐 (TiTp2) 显示了最高的燃烧热量,表明其作为强大的燃料来源的潜力.
科学领域:
- 无机化学 无机化学 有机化学
- 热化学 热化学 热化学
- 材料科学 材料科学 材料科学
背景情况:
- 具有三 (pyrazolyl) 酸盐 (Tp) 连接体的金属复合物因其多样化的化学性质而引起人们的兴趣.
- 了解这些化合物的能量含量对于储能和催化应用至关重要.
研究的目的:
- 通过实验确定和理论计算MgTp2,FeTp2,MnTp2和TiTp2.2的能量含量.
- 为了比较这些金属复合物的燃烧能量.
- 根据其燃烧能量评估Ti(II) 作为燃料原子的潜力.
主要方法:
- 炸弹热量计被用来测量每个化合物的燃烧热量.
- 实验结果与理论计算进行了比较.
主要成果:
- 在研究的化合物中, (II) 三 (pyrazolyl) 酸盐 (TiTp2) 的燃烧热量最高.
- 与MgTp2和MnTp2相比,TiTp2的燃烧热量表明Ti (II) 的有效燃烧能量在1400到3000kJ/mol之间.
结论:
- 实验数据证实TiTp2具有最大的能量含量.
- 这些发现证实了Ti (II) 氧化状态的显著燃料潜力.
相关概念视频
Nuclear Transmutation
17.6K
Nuclear transmutation is the conversion of one nuclide into another. It can occur by the radioactive decay of a nucleus, or the reaction of a nucleus with another particle. The first manmade nucleus was produced in Ernest Rutherford’s laboratory in 1919 by a transmutation reaction, the bombardment of one type of nuclei with other nuclei or with neutrons. Rutherford bombarded nitrogen-14 atoms with high-speed α particles from a natural radioactive isotope of radium and observed...
17.6K
Nuclear Fusion
23.2K
The process of converting very light nuclei into heavier nuclei is also accompanied by the conversion of mass into large amounts of energy, a process called fusion. The principal source of energy in the sun is a net fusion reaction in which four hydrogen nuclei fuse and ultimately produce one helium nucleus and two positrons.
A helium nucleus has a mass that is 0.7% less than that of four hydrogen nuclei; this lost mass is converted into energy during the fusion. This reaction produces about...
A helium nucleus has a mass that is 0.7% less than that of four hydrogen nuclei; this lost mass is converted into energy during the fusion. This reaction produces about...
23.2K
Radioactivity and Nuclear Equations
21.2K
Nuclear chemistry is the study of reactions that involve changes in nuclear structure. The nucleus of an atom is composed of protons and, except for hydrogen, neutrons. The number of protons in the nucleus is called the atomic number (Z) of the element, and the sum of the number of protons and the number of neutrons is the mass number (A). Atoms with the same atomic number but different mass numbers are isotopes of the same element.
A nuclide of an element has a specific number of protons and...
A nuclide of an element has a specific number of protons and...
21.2K
Atomic Absorption Spectroscopy: Atomization Methods
593
Atomic Absorption Spectroscopy (AAS) atomizes samples through flame atomization or electrothermal atomization. Flame atomization typically involves a nebulizer and spray chamber assembly to combine the sample with a fuel–oxidant mixture, creating a fine aerosol mist that enters a burner. Typically, the fuel and oxidant are combined in an approximately stoichiometric ratio. However, for atoms that are easily oxidized, a fuel-rich mixture may be more advantageous. Only about 5% of the...
593
Nuclear Fission
9.8K
Many heavier elements with smaller binding energies per nucleon can decompose into more stable elements that have intermediate mass numbers and larger binding energies per nucleon—that is, mass numbers and binding energies per nucleon that are closer to the “peak” of the binding energy graph near 56. Sometimes neutrons are also produced. This decomposition of a large nucleus into smaller pieces is called fission. The breaking is rather random with the formation of a large...
9.8K
Ionization Energy
34.0K
The amount of energy required to remove the most loosely bound electron from a gaseous atom in its ground state is called its first ionization energy (IE1). The first ionization energy for an element, X, is the energy required to form a cation with 1+ charge:
34.0K


