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探索激光生成的从一个合聚合物中的exciplex的光动力学特征

O Aldaghri¹, Ahmed Alsadig², Hajo Idriss¹

¹Imam Mohammad Ibn Saud Islamic University (IMSIU), College of Science, Physics Department, P.O. Box 13318, Saudi Arabia.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy

|June 2, 2023

概括

这项研究探讨了度如何影响THF中聚二二二三二甲基基 (PDDCP) 的光谱特性. PDDCP表现出度依赖的光发光和超辐射放大自发发射 (ASE) 峰值,表明光学设备的潜力.

科学领域:

材料科学材料科学材料科学
聚合物化学聚合物化学
光电学是指光电子产品.

背景情况:

导电聚合物对于先进的电子和光学应用至关重要.
了解像PDDCP这样的聚合物的光物理性质对于设备优化至关重要.
聚二二二三二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二

研究的目的:

调查PDDCP在四二 (THF) 中度对光谱和放大自发发射 (ASE) 特性的影响.
分析度对吸收,光发光 (PL) 和能量带间隙的影响.
为了确定从PDDCP.中超辐射ASE辐射的最佳条件.

主要方法:

在不同度 (1-100μg/mL) 的PDDCP溶液的光谱分析 (吸收,光发光).
在特定的脉冲能量下测量放大自发发射 (ASE) 光谱.
对聚合物聚合和能量频段间隙变化的分析与度.

主要成果:

吸收光谱在330和445纳米处显示出一致的峰值,不受度的影响.
光发光谱和能量波段间隙随度而变化,表明了exciplex/excimer形成.
一个超辐射的ASE峰值在565nm与狭窄的FWHM被观察到在25μg/mL和3mJ能量.

结论:

度显著影响PDDCP的光物理性质,特别是PL和带隙.
在研究的度范围内,PDDCP不会在基态中聚合.
观察到的超辐射ASE表明PDDCP在可调节激光器,二极管和太阳能电池中的潜在应用.

关键词:

在ASE中,ASE是ASE.结合聚合物的聚合物.能量带差距差距的能量带差距光学属性光学属性在PDDCPCP中使用.

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