全聚合物混合物中的激发状态动力学与聚合小分子受体的聚合
概括
聚合小分子接受器 (PSMA) 改善了全聚合物太阳能电池中的电荷分离. 然而,改变的分子包装会影响激发状态的动态,影响设备的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 太阳能光伏发电是如何实现的
- 聚合物化学 聚合物化学
背景情况:
- 全聚合物太阳能电池 (全PSC) 使用聚合物接受器提高性能.
- 将小分子受体 (SMA) 聚合成聚合物受体 (PSMA) 改变了分子包装和兴奋状态动态.
- 了解PSMA中的分子包装和兴奋状态动态之间的联系对于优化所有PSC效率至关重要.
研究的目的:
- 研究聚合型SMA (PSMA) 和它们的小分子对应物 (SMA) 的兴奋状态动态和分子包装.
- 阐明基于PSMA的全聚合物太阳能电池中分子包装修饰和兴奋状态动态之间的关系.
- 通过操纵分子包装和兴奋状态动态来确定优化所有PSC性能的策略.
主要方法:
- 激发状态动力学和分子包装的实验研究.
- 理论计算来补充实验发现.
- 在混合系统中对PSMA和SMA进行比较分析.
主要成果:
- 含有PSMA的混合物中的电荷分离速度更快,这是由于内部分离状态 (i-DEs) 的原因.
- 在PSMA中较宽松的π-π分子包装抑制了从局部激发 (LE) 到i-DEs的激发转换,增加了辐射损失.
- 增加PSMA聚合减少了捐助者:受体接口,减少了来自双分子电荷重组的三倍损失.
结论:
- 分子包装显著影响PSMAs中的兴奋状态动态.
- 在PSMA中优化分子包装可以减轻辐射损失和减少三倍损失.
- 定制分子包装为提高全聚合物太阳能电池性能提供了一条途径.
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