超临界CO2的影响
Xicong Ma1, Yi Du1,2, Changqing Fu3
1National and Local Joint Engineering Research Center for Carbon Capture Utilization and Sequestration & State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi'an 710069, China.
超临界的二氧化碳和水通过创建新的孔隙和断裂来改变煤炭的孔隙结构. 矿物质溶解,特别是石,对不同孔径的孔隙体积,表面积和复杂性产生重大影响.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 煤炭科学 煤炭科学
背景情况:
- 煤炭孔状结构对于储能和碳捕获至关重要.
- 在超临界条件下了解矿物煤相互作用对于优化这些过程至关重要.
研究的目的:
- 为了研究超临界CO2 (ScCO2) -H2O-煤炭相互作用对煤炭孔隙结构的影响.
- 分析矿物产生的煤炭多孔性和表面积的变化.
主要方法:
- 模拟ScCO2-H2O-煤炭相互作用的自体实验.
- 侵入毛细血管压力 (MICP),和二氧化碳吸附,以及FESEM分析.
- 碎形理论的应用来量化毛孔复杂性.
主要成果:
- ScCO2-H2O处理显著增加了煤孔体积和特定表面积,形成了新的孔隙和断裂.
- 完整的石溶解导致更大的毛孔 (>150 nm) 具有统一的形态和减少的碎形尺寸.
- 不完整的石溶解导致更复杂的孔隙结构 (2-150 nm) 与增加的碎形尺寸.
- 微孔 (<2 nm) 在反应后变得更加均,碎形尺寸减少.
结论:
- 水的存在增强了ScCO2与煤炭的相互作用,可能提高了CO2的注入性.
- 矿物质溶解,特别是石,是在ScCO2-H2O条件下的煤孔结构演变的关键驱动因素.
- 碎形尺寸有效地描述了由于矿物质变化的煤孔的复杂性变化.
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