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Minoo Khodamorady1, Kiumars Bahrami1,2
1Department of Organic Chemistry, Faculty of Chemistry, Razi University, Kermanshah 67144-14971, Iran.
Heliyon
|June 5, 2023
概括
新的磁性纳米复合材料在紫外线和可见光下有效地去除染料和废水. 最好的光催化剂MNPs@BNPs@ZnO-ZnS (0.75:0.25),表现出优异的性能和减少的电子孔重组.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 纳米技术纳米技术
背景情况:
- 开发高效的光催化剂对于环境修复至关重要.
- 磁纳米复合材料为污染物降解提供可调节的特性.
- 基于氧化和硫化的材料在光催化中表现有前途.
研究的目的:
- 合成新的磁性纳米复合材料 (MNPs@BNPs@ZnO-ZnS) 具有不同的ZnO/ZnS摩尔比.
- 评估它们在紫外线和可见光下去除甲基蓝 (MB),甲基 (MO) 和真实污水的光催化效率.
- 确定最佳的纳米复合材料组成,并了解其性能特征.
主要方法:
- 合成具有不同ZnO/ZnS摩尔比的磁性纳米复合材料.
- 在紫外线和可见光下使用MB,MO和真实废水进行光催化降解实验.
- 使用传输电子显微镜 (TEM),动态光散射 (DLS) 采用泽塔电位和光发光 (PL) 光谱学进行表征.
- 动力学研究以确定降解速率常数.
主要成果:
- 最好的光催化剂MNPs@BNPs@ZnO-ZnS (ZnO/ZnS:0.75:0.25) 显示出最高的效率,特别是在紫外线下.
- 合成的纳米复合材料颗粒大小在10-30nm之间.
- PL分析表明,在最佳光催化剂中,电子孔再组合减少.
- 移除MO和MB的速率常数分别为0.0186分钟-1和0.0171分钟-1.
- 在大多数pH值下,光催化剂表现出负表面电荷.
结论:
- 新型MNPs@BNPs@ZnO-ZnS纳米复合物 (0.75:0.25比) 是一种高效的光催化剂,用于降解有机染料和废水.
- 该材料的效率归因于电荷载体重组减少和最佳组成.
- 使用廉价,耐用,高效的紫外线和可见光灯使其成为废水处理的实用解决方案.
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