研究基本O的吸附-扩散行为
Wei Liu1, Minghui Qi2, Xiangyu Chu2
1School of Emergency Management and Safety Engineering, China University of Mining and Technology-Beijing, Beijing, 100083, China. liuwei7230@cumtb.edu.cn.
温度显著影响煤炭中的气体吸附和扩散,这对于理解煤炭自燃 (CSC) 至关重要. 高温降低了气体吸附,但增加了扩散,这一发现与自由气体密度梯度扩散 (FDGD) 模型相一致.
科学领域:
- 地质化学 地质化学
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
背景情况:
- 煤炭自燃 (CSC) 受煤炭内部气体吸附-扩散行为的影响.
- 在CSC过程中,温度是控制煤炭中气体迁移的关键因素.
- 了解气煤相互作用对于预测和预防CSC至关重要.
研究的目的:
- 为了研究O2,CO2和N2在不同温度下的煤和炭酸煤中的吸附-扩散特性.
- 量化评估温度对煤中的气体迁移的影响.
- 为了验证在不同的温度条件下自由气体密度梯度扩散 (FDGD) 模型的适用性.
主要方法:
- 同热吸附实验是在0.5MPa和各种温度的煤样本上进行的.
- 使用自由气体密度梯度扩散 (FDGD) 模型来计算微通道扩散系数.
- 分析了实验数据和模拟结果,以评估温度影响.
主要成果:
- 气体对O2,CO2和N2的吸附能力随着温度的增加而下降,按照CO2 > O2 > N2的顺序.
- FDGD模型准确地描述了这些气体在不同温度的煤炭中的吸附-扩散行为.
- 三种气体的微通道扩散系数 (Km) 随着温度的上升而增加.
结论:
- 温度对煤炭中的气体吸附和扩散动态产生重大影响.
- FDGD模型为研究在不同热条件下煤炭中的气体迁移提供了可靠的框架.
- 这项研究提高了对煤炭自燃相关气体迁移机制的理解.
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