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Updated: Jul 27, 2025

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σ-环基到π-基重排在Au的位置

Marte S M Holmsen1,2,3, David Vesseur1, Yago García-Rodeja4

  • 1CNRS/Université Paul Sabatier, Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA, UMR 5069), 118 Route de Narbonne, 31062, Toulouse Cedex 09, France.

Angewandte Chemie (International ed. in English)
|June 6, 2023
PubMed
概括

黄金 (III) 环基复合物可以通过环开放转化为π-基复合物. 这种反应即使在低温下也很快发生,这取决于附属连接物附着在黄金中心.

关键词:
作为一个敌人,Agostic.循环烯基 循环烯基黄金 黄金 黄金 黄金调整的重新安排π-基化物 基化物 π-基化物

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