Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Catalysis02:50

Catalysis

27.1K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
27.1K
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

3.4K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
3.4K
Preparation of Amines: Alkylation of Ammonia and Amines01:30

Preparation of Amines: Alkylation of Ammonia and Amines

3.5K
Alkylation is one of the methods used to prepare amines. Direct alkylation of ammonia or a primary amine with an alkyl halide gives polyalkylated amines along with a quaternary ammonium salt through successive SN2 reactions. This process of making the quaternary salt through the direct alkylation method is called exhaustive alkylation.
Each alkylation step makes the nitrogen center more nucleophilic, which triggers successive alkylations until a quaternary ammonium salt is formed. Considering...
3.5K
Preparation of 1° Amines: Gabriel Synthesis01:28

Preparation of 1° Amines: Gabriel Synthesis

3.6K
Direct alkylation is not a suitable method for synthesizing amines because it produces polyalkylated products. Gabriel synthesis is the most preferred method to exclusively make primary amines. The method uses phthalimide, which contains a protected form of nitrogen that participates in alkylation only once to predominantly give primary amines.
Strong bases like NaOH or KOH deprotonate the phthalimide to form the corresponding anion, which acts as a nucleophile. Further, the anion attacks an...
3.6K
Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

12.2K
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
12.2K
Reduction of Alkynes to trans-Alkenes: Sodium in Liquid Ammonia02:10

Reduction of Alkynes to trans-Alkenes: Sodium in Liquid Ammonia

9.3K
Alkynes can be reduced to trans-alkenes using sodium or lithium in liquid ammonia. The reaction, known as dissolving metal reduction, proceeds with an anti addition of hydrogen across the carbon–carbon triple bond to form the trans product. Since ammonia exists as a gas (bp = −33°C) at room temperature, the reaction is carried out at low temperatures using a mixture of dry ice (sublimes at −78°C) and acetone. 
When dissolved in liquid ammonia, an alkali metal,...
9.3K

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

Engineering CO<sub>2</sub> Reduction Pathways via Alloy-Support Interactions in Li-CO<sub>2</sub> Batteries.

Advanced materials (Deerfield Beach, Fla.)·2026
Same author

Engineering Nanodiamonds for Quantum Sensing: Material Constraints at the Nanoscale.

ACS nano·2026
Same author

Ordered Ionic-Liquid Channels Enable Fast Anhydrous Proton Conduction at up to 240°C for Fuel Cells.

Angewandte Chemie (International ed. in English)·2026
Same author

Geometry-Controlled Synergy of Adjacent Cu(I) Sites Enhances C-C Coupling for Efficient CO<sub>2</sub>-to-C<sub>2+</sub> Electroreduction.

Journal of the American Chemical Society·2026
Same author

Mass-Transport Effects in the Lithium Redox-Mediated Nitrogen Reduction Reaction.

Journal of the American Chemical Society·2026
Same author

Implications of Structural Disorder for the Electrocatalytic Properties of MoS<sub>2</sub> Materials.

Journal of the American Chemical Society·2026

相关实验视频

Updated: Jul 27, 2025

Ammonia Synthesis at Low Pressure
08:14

Ammonia Synthesis at Low Pressure

Published on: August 23, 2017

26.6K

调催化剂对氨的选择性

C Felipe Garibello1, Alexandr N Simonov2, Shery L Y Chang3

  • 1Department of Chemistry and Biotechnology, School of Science, Computing and Engineering Technologies, Swinburne University of Technology, Hawthorn, Victoria 3122, Australia.

Inorganic chemistry
|June 6, 2023
PubMed
概括
此摘要是机器生成的。

(Mo) 与硫化铁共同降落,形成基于固体几何学的独特材料. 大约10%的Mo优化了从亚酸盐中生产的,同时最大限度地减少了气的形成.

更多相关视频

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
08:40

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

Published on: December 6, 2021

3.6K
Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
10:19

Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation

Published on: July 18, 2017

12.0K

相关实验视频

Last Updated: Jul 27, 2025

Ammonia Synthesis at Low Pressure
08:14

Ammonia Synthesis at Low Pressure

Published on: August 23, 2017

26.6K
Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
08:40

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

Published on: December 6, 2021

3.6K
Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
10:19

Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation

Published on: July 18, 2017

12.0K

科学领域:

  • 生物有机化学 生物有机化学
  • 催化剂的研究研究.
  • 材料科学是一种材料科学.

背景情况:

  • 硫化铁在金属蛋白催化中至关重要,特别是在酶酶中.
  • 在硫化铁集群中加入二级金属,如 (Mo),为酶进化提供了洞察力.

研究的目的:

  • 为了研究与硫化铁的共降.
  • 评估这些Mo-Fe-S材料在还原反应中的催化活性.

主要方法:

  • 采用X射线吸收光谱 (XAS) 来描述合成的Mo-Fe-S材料.
  • 这些材料作为催化剂和直接还原剂使用化物 (NO2-) 和质子 (H+) 作为基质进行了测试.

主要成果:

  • 与硫化铁共同沉,形成不同的结构,取决于Mo,Fe和硫化铁 (HS-) 的摩尔比率.
  • 降解产品的选择性受含量的影响.
  • 发现大约10%的Mo含量优化了从NO2-中产生的氨/氨 (NH4+/NH3) 产量,并抑制了从H+中产生的 (H2) 形成.

结论:

  • 这项研究证明了具有可调节的催化性能的Mo-Fe-S材料的受控合成.
  • 硫化铁催化剂的优化Mo含量提高了对所需的还原产品的选择性,这对理解金属酶功能和开发新催化剂很重要.