半豪斯勒合金作为新兴的高功率密度热电冷却材料
Hangtian Zhu1,2, Wenjie Li3, Amin Nozariasbmarz4
1Department of Materials Science and Engineering, Pennsylvania State University, University Park, PA, 16802, USA. htzhu@iphy.ac.cn.
Nature communications
|June 6, 2023
概括
通过缺陷控制优化半斯勒 (hH) 材料显著提高了热电性能. 这项研究实现了创纪录的zT~0.86,提高了近室温应用的冷却功率和效率.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 热电学是一种热电学.
背景情况:
- 优化热电性能需要解声和电子运输.
- 半海斯勒 (hH) 化合物由于弱的电子声学声子相互作用而具有潜力.
- 选择性缺陷减少是提高hH材料性能的关键.
研究的目的:
- 为了研究Sb压力控制的回火对Nb0.55Ta0.40Ti0.05FeSb的微观结构和缺陷的影响.
- 为了提高半海斯勒化合物的热电特性,用于实际应用.
主要方法:
- 使用Sb压力控制的回火工艺来调节微结构和点缺陷.
- 描述了修改后的Nb0.55Ta0.40Ti0.05FeSb化合物的热电特性.
- 使用优化材料评估设备性能.
主要成果:
- 实现了100%的载体移动性增加,最大功率系数为78μW cm-2 K-2.2.
- 在300-873 K.之间获得了最高的hH化合物的平均功率 (zT) ~0.86的平均值.
- 与Bi2Te3设备相比,冷却功率密度提高了210%和转换效率提高了12%.
结论:
- Sb压力控制的回火是优化hH热电材料的有效策略.
- 开发的材料对接近室温的热电冷却应用具有显著的前景.
- 这项工作推动了高性能热电设备的开发.
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