关于净氧的理论预测作为一个有前途的/离子电池阳极
Chunlai Huang1,2, Junping Hu1,2, Chuying Ouyang3
1Nanchang Key Laboratory of Photoelectric Conversion and Energy Storage Materials, Nanchang Institute of Technology Nanchang 330099 China.
RSC advances
|June 7, 2023
概括
新的二维氧化 (l-B2O) 显示出离子和离子电池的前景. 这种材料具有高容量和出色的稳定性,使其成为石墨阳极的潜在替代品.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 计算化学的计算化学
背景情况:
- 二维 (2D) 材料正在成为下一代储能设备的先进电极候选者.
- 离子电池 (LIB) 和离子电池 (NIB) 对于便携式电子设备和电网存储至关重要.
研究的目的:
- 研究一种新的二维氧化 (l-B2O) 材料对LIB和NIB的潜力.
- 使用第一原则计算系统地分析l-B2O的和储存特性.
主要方法:
- 第一个原则的计算被用于几何优化.
- 评估和吸附和迁移过程.
- 评估特定容量和平均开通电路电压.
主要成果:
- l-B2O具有良好的导电性和低的Li/Na扩散障碍,表明其速度性能优越.
- 该材料在离子吸附时表现出很小的晶格变化 (<1.7%),确保了良好的循环稳定性.
- 和纳储存的理论特异容量分别达到1068.5和712.3mA hg-1,明显超过石墨.
结论:
- 2Dl-B2O是对LIB和NIB都非常有前途的阳极材料.
- 它的优良电化学性能和结构稳定性使其成为传统阳极材料的竞争性替代品.
相关概念视频
Ionic Bonding and Electron Transfer
41.8K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
41.8K
Hydroboration-Oxidation of Alkenes
8.5K
In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
8.5K
Batteries and Fuel Cells
27.7K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.7K
Electrolysis
26.9K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.9K
Alkali Metals
19.4K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
19.4K
Ionic Compounds: Formulas and Nomenclature
67.3K
An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
67.3K


