一个湿度诱导的大电子导电性变化10的变化
Wei-Hua Deng1,2, Qiao-Hong Li1, Jie Chen1
1State Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
Angewandte Chemie (International ed. in English)
|June 8, 2023
概括
水显著提高了改性金属有机框架 (MOF) 的电子导电性 (EC). 这一发现使得先进的湿度传感器能够开发出前所未有的性能,展示MOF.
科学领域:
- 材料科学 材料科学 材料科学
- 化学 化学 化学
- 纳米技术纳米技术
背景情况:
- 金属有机框架 (MOF) 中的电子导电性 (EC) 通常对氧化剂敏感.
- 水 (H2O),一种温和物种,对MOF EC的影响被低估.
- 了解H2O的影响对于新的MOF应用至关重要.
研究的目的:
- 研究H2O对 (NH2) 2-MIL-125及其衍生物的EC的影响.
- 探索H2O诱导的EC变化背后的机制.
- 根据这些发现,开发高性能传感材料.
主要方法:
- 在 (NH2) 2-MIL-125和H2SO4@(NH2) 2-MIL-125.5上的实验研究.
- 对负担转移机制的理论研究.
- 化学阻抗湿度传感器的制造和测试.
主要成果:
- 在暴露于H2O时,观察到H2SO4@(NH2) 2-MIL-125的EC显著增加107倍.
- 布伦斯特酸对和H2SO4促进了从H2O到MOF的电荷转移.
- 一个新的湿度传感器显示出卓越的灵敏度,检测范围和检测极限.
结论:
- H2O可以显著影响MOFs的EC.
- 对MOF的后修改增强了H2O对EC的影响.
- 这项研究为设计基于MOF的先进传感材料铺平了道路.
相关概念视频
Electrical Conductivity
1.2K
In perfect conductors, the electric field inside is always zero due to the abundance of free electrons, which nullify any field by flowing. As a result, any residual charge resides on the surface.
In a practical conductor, an applied electric field may be sustained, causing a flow of electrons, which produce a current. The differential form of the current, the current density, is related to the electric field.
More generally, it is related to the force per unit charge, which involves the...
In a practical conductor, an applied electric field may be sustained, causing a flow of electrons, which produce a current. The differential form of the current, the current density, is related to the electric field.
More generally, it is related to the force per unit charge, which involves the...
1.2K
Resistivity
3.6K
When a voltage is applied to a conductor, an electrical field is generated, and charges in the conductor feel the force due to the electrical field. The current density that results depends on the electrical field and the properties of the material. In some materials, including metals at a given temperature, the current density is approximately proportional to the electrical field. In these cases, the current density can be modeled as:
3.6K
Theory of Metallic Conduction
1.4K
The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
1.4K
Electrolyte and Nonelectrolyte Solutions
63.3K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
63.3K
Susceptibility, Permittivity and Dielectric Constant
1.6K
When placed in an external electric field, a dielectric material gets polarized. The charge density in the dielectric material is given by the sum of the bound and free charge densities, while the total charge density can also be written in terms of the total electric field. The bound charge density can be measured in terms of polarization, leading to the relationship between electric displacement and polarization.
1.6K
Electrolytes: van't Hoff Factor
33.3K
Colligative Properties of Electrolytes
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
33.3K


