在石铁电器中进行原子尺度偏振切换
Sebastian Calderon1, John Hayden2, Steven M Baksa2
1Department of Materials Science and Engineering, Carnegie Mellon University, Pittsburgh, PA 15213, USA.
概括
铁电石对微电子有希望,但需要较低的交换场来实现CMOS兼容性. 原子尺度成像揭示了极化逆转机制,包括石环的平坦化,为材料性能工程铺平了道路.
科学领域:
- 材料科学
- 固态物理
- 纳米技术
背景情况:
- 铁电工厂为微电子提供了整合潜力.
- 当前的极化切换场阻碍了金属氧化物半导体 (CMOS) 的兼容性.
研究的目的:
- 了解和量化铁电石中的原子尺度偏振切换机制.
- 为实际应用确定减少切换场的途径.
主要方法:
- 使用扫描传输电子显微镜 (STEM) 的实时原子尺度观测.
- 第一个原则是模拟反转能量和中间阶段.
主要成果:
- 在Al0.94B0.06N中观察到一个极化逆转模型,其中包括的石环的平坦化.
- 在极化切换过程中发现过渡的非极性几何形状.
- 模拟证实在逆转过程中的反极阶段.
结论:
- 这项研究提供了铁电石极化切换的详细原子尺度模型.
- 这种机理理解对于设计具有较低开关场的铁电工艺具有至关重要的意义.
- 能够在未来开发这些材料用于先进的电子和光学设备.
相关概念视频
Dielectric Polarization in a Capacitor
4.8K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
4.8K
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Potential Due to a Polarized Object
443
A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
443
Biasing of Metal-Semiconductor Junctions
288
Biasing metal-semiconductor junctions involves applying a voltage across the junction. Specifically, the metal is connected to a voltage source, while the semiconductor is grounded. This technique is essential for controlling the direction and magnitude of current flow in electronic devices, including diodes, transistors, and photovoltaic cells.
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
288
Crystal Field Theory - Tetrahedral and Square Planar Complexes
43.2K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
43.2K
Induced Electric Dipoles
4.3K
A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
4.3K


