低度的NO可增强大气中高氧化生物分子的形成
Wei Nie1,2,3, Chao Yan4,5,6, Liwen Yang4
1Joint International Research Laboratory of Atmospheric and Earth System Research, School of Atmospheric Sciences, Nanjing University, Nanjing, China. niewei@nju.edu.cn.
Nature communications
|June 8, 2023
概括
低氧化 (NO) 度可以令人惊地增强高氧化有机分子 (HOM) 的形成. 这挑战了以前关于NO的假设.
科学领域:
- 大气化学 大气化学
- 气溶科学 气溶科学
- 有机化学 有机化学
背景情况:
- 高氧化有机分子 (HOM) 是二次有机气溶的关键前体.
- 氧化 (NO) 和有机过氧基 (RO2) 之间的相互作用影响HOM形成.
- 以前的理解表明,即使在低度下,NO也会抑制HOM的产生.
研究的目的:
- 在非常低的NO度 (0-82 pptv) 中从单烯中研究HOM的形成.
- 重新评估NO对RO2基化学和随后的自氧化的影响.
- 挑战关于NO在抑制HOM产量的作用的既定观点.
主要方法:
- 专门进行了实验室实验.
- 在受控的低NO条件下,专注于单烯氧化.
- 对HOM形成路径和产量的分析.
主要成果:
- 发现低NO度 (0-82 pptv) 可以增强HOM的产生.
- 这种增强通过调节RO2基损失通路而发生.
- 有利于形成通过异构化促进进一步自氧化的基基.
结论:
- 来自北极森林排放的HOM产量可能在2.5%-6.5%之间.
- 即使在高NO度下,HOM的形成也无法完全抑制.
- 这些发现将RO2-NO相互作用的知识扩展到低NO体制,这对工业化前和原始环境至关重要.
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