一种双层高温介电薄膜,具有优越的分解强度和储能密度
Jiang-Bo Ping1, Qi-Kun Feng1, Yong-Xin Zhang1
1State Key Laboratory of Power System, Department of Electrical Engineering, Tsinghua University, Beijing, 100084, People's Republic of China.
Nano-micro letters
|June 8, 2023
概括
研究人员通过涂层聚乙烯二甲酸 (PET) 薄膜与化纳米片 (BNNS) 来提高薄膜电容器的性能. 这种修改显著提高了电气化应用中至关重要的断裂强度和能量密度.
科学领域:
- 材料科学 材料科学 材料科学
- 电气工程 电气工程
- 纳米技术 纳米技术
背景情况:
- 电气化需要提高电容器性能,特别是薄膜电容器.
- 电容器的能量密度取决于介电材料的分解强度和介电常数.
- 同时提高断裂强度和介电常数是一个重大挑战.
研究的目的:
- 为了提高薄膜电容器的性能.
- 为了克服同时提高断裂强度和介电常数的挑战.
- 探索使用化纳米片 (BNNS) 来修改聚合物薄膜.
主要方法:
- 通过使用溶液造将聚乙烯二甲 (PET) 薄膜涂在BNNS上,制成双层聚合物薄膜.
- 使用紫外线吸收光谱,泄漏电流测量和有限元计算,研究了带隙和绝缘行为.
- 评估了在高温下修改过的薄膜的性能.
主要成果:
- BNNS纳米涂层增强了聚合物薄膜的带隙,抑制了电荷注入.
- 实现了超高的分解场强度 (736 MV/m),高放电能量密度 (8.77 J/cm3) 和优异的电荷-放电效率 (96.51%).
- 经过修改的PET薄膜在高温 (120°C) 上表现出优越的性能.
结论:
- BNNS超薄层显著促进了电容器性能的提高.
- 易于使用和易于使用的改造方法适合大规模的卷对卷生产.
- 这项工作对于开发商业上可行的电容膜改造具有重要意义.
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