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Updated: Jul 27, 2025

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

Published on: February 15, 2016

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通过在纳米尺寸的三三中逐步的轴坐标调节超分子性 (chirality)

Avinash Dhamija1, Dolly Chandel1, Sankar Prasad Rath1

  • 1Department of Chemistry, Indian Institute of Technology Kanpur Kanpur-208016 India sprath@iitk.ac.in.

Chemical science
|June 9, 2023
PubMed
概括

一种新型的Achiral trizinc (((ii) porphyrin trimer宿主表现出类似弹的运动和单向扭曲,在绑定 chiral diamine 客人时. 这种超分子复合体形成会诱导可调的氨酸循环二元化 (CD) 反应,为分子性提供了洞察力.

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Isomerism in Complexes
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Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
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