在动力控制下双胞胎繁殖和延长:Pd-Au Janus Icosahedra
Xiaoyu Qiu1,2, Veronica Pawlik3, Shan Zhou3
1The Wallace H. Coulter Department of Biomedical Engineering, Georgia Institute of Technology and Emory University, Atlanta, Georgia 30332, United States.
Journal of the American Chemical Society
|June 9, 2023
概括
研究人员在 (Pd) 纳米晶体上开发了两种新的金 (Au) 原子生长模式,为先进的应用创造了独特的Janus icosahedra和星形核心外结构.
科学领域:
- 材料科学
- 纳米技术
- 催化剂
背景情况:
- 具有特定结构和缺陷的异质双金属纳米晶体提供了增强的催化和光子特性.
- 控制纳米晶体形态是调整它们性能的关键.
研究的目的:
- 在五双 (Pd) 十面体上研究两种不同的黄金 (Au) 增长模式.
- 了解控制这些生长模式和由此产生的纳米晶体结构的机制.
主要方法:
- 使用控制的Au (III) 离子注入速率合成双金属Pd-Au纳米晶体.
- 使用先进技术对纳米晶体形态,构成和应变的描述.
- 增长动力学和表面扩散效应的机制分析.
主要成果:
- 确定了两种生长模式:形成不对称的Pd-Au Janus icosahedra的双胞胎繁殖和形成异型的Pd@Au核心贝海星的双胞胎延伸.
- 离子的下限数量 (nlow) 决定了增长模式,受注射速率和表面扩散的影响.
- 雅努斯·伊科萨赫德拉表现出高拉伸力 (2.2 GPa) 和拉伸差 (+21.9%).
- Pd@Au海星显示可调节的大小 (28-40 nm) 和显著的晶格扩张 (8.82-20.10%).
结论:
- (III) 离子的注入速率是控制双金属纳米晶体生长的关键因素.
- 精确设计的具有独特形态的Pd-Au纳米晶体可用于定制的催化和光子应用.
相关概念视频
Centrosome Duplication
4.1K
The primary microtubule organizing center (MTOC) in animal cells is the centrosome. A centrosome has two cylindrical centrioles at its core. Each centriole consists of nine sets of three microtubules held together by proteins. The centrioles are positioned at right angles to each other and surrounded by a shapeless protein cloud called the pericentriolar matrix, or pericentriolar material (PCM).
To ensure that each daughter cell receives a centrosome after cell division, centrosome duplication...
To ensure that each daughter cell receives a centrosome after cell division, centrosome duplication...
4.1K
Polytene Chromosomes
10.1K
Polytene chromosomes are giant interphase chromosomes with several DNA strands placed side by side. They were discovered in the year 1881 by Balbiani in salivary glands, intestine, muscles, malpighian tubules, and hypoderm of larvae Chironomus plumosus. Hence, these are also called "Salivary gland chromosomes." These are found in insects of the order Diptera and Collembola; in certain organs of mammals; and synergids, antipodes of flowering plants. Polytene chromosomes are also...
10.1K
Radical Chain-Growth Polymerization: Mechanism
2.6K
The radical chain-growth polymerization mechanism consists of three steps: initiation, propagation, and termination of polymerization. The polymerization initiates when a free radical generated from the radical initiator adds to the unsaturated bond in the monomer. The unpaired electron of the free radical and one π electron in the unsaturated bond creates a σ bond between the free radical and the monomer. As a result, the other π electron in the unsaturated bond converts this...
2.6K
Ziegler–Natta Chain-Growth Polymerization: Overview
3.4K
Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta...
3.4K
Anionic Chain-Growth Polymerization: Mechanism
2.1K
The mechanism for anionic chain-growth polymerization involves initiation, propagation, and termination steps. In the initiation step, a nucleophilic anion, such as butyl lithium, initiates the polymerization process by attacking the π bond of the vinylic monomer. As a result, a carbanion, stabilized by the electron‐withdrawing group, is generated. The resulting carbanion acts as a Michael donor in the propagation step and attacks the second vinylic monomer, which acts as a Michael...
2.1K
Abnormal Proliferation
4.6K
Under normal conditions, most adult cells remain in a non-proliferative state unless stimulated by internal or external factors to replace lost cells. Abnormal cell proliferation is a condition in which the cell's growth exceeds and is uncoordinated with normal cells. In such situations, cell division persists in the same excessive manner even after cessation of the stimuli, leading to persistent tumors. The tumor arises from the damaged cells that replicate to pass the damage to the...
4.6K


