通过固体采样,电热蒸发与感应合等离子光学发射光谱学相结合的法医分析
Kate Moghadam1, Diane Beauchemin1
1Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, ON K7L 3N6, Canada. diane.beauchemin@queensu.ca.
概括
固体采样电热蒸发与感应合等离子光学发射光谱学 (ETV-ICPOES) 结合,为法医痕迹证据分析提供了一种敏感的方法. 这种技术允许使用最小的样本数量精确识别和区分证据.
科学领域:
- 法医科学 法医科学 法医科学
- 分析化学 分析化学
- 频谱测量是一种光谱测量.
背景情况:
- 法医痕迹证据分析需要非破坏性或最小样本技术.
- 固体采样电热蒸发与感应合的等离子光学发射光谱学 (ETV-ICPOES) 是一种合适的技术,只需要0.1-5毫克的样品.
研究的目的:
- 讨论ETV-ICPOES在法医证据分析方面的能力.
- 突出其在识别,确定和歧视证据方面的价值.
主要方法:
- 审查ETV-ICPOES用于直接分析实物和痕迹证据的方法.
- 应用矩阵匹配的外部校准和内部标准化.
- 使用多变量分析 (PCA,LDA) 进行定性多元件分析.
主要成果:
- ETV-ICPOES展示了证据识别和歧视的各种机会.
- 方法允许对多个元素进行量化和定性多元元素分析.
- 内部标准化有效地弥补了样本加载效应.
结论:
- ETV-ICPOES是法医追踪证据分析的一个有价值的工具.
- 最新的进展为证据审查提供了多样化的机会.
- 未来的法医设置可以从ETV-ICPOES的利用中受益.
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