在Fe (Oxyhydr) 氧化物上吸附期间从EXAFS中揭示的抗同位素分离
Weiqing Zhou1,2,3, Jianwei Zhou1,2,3, Xinbin Feng4
1School of Environmental Studies, China University of Geosciences, Wuhan 430074, China.
Environmental science & technology
|June 9, 2023
概括
在吸附到铁 (oxyhydr) 氧化物时, (Sb) 同位素的分离是由同位素平衡驱动的. 这一过程对于环境追踪至关重要,显示较轻的Sb同位素优先富含铁矿物质.
科学领域:
- 地质化学 地质化学
- 环境科学 环境科学
- 同位素地球化学 同位素地球化学
背景情况:
- 在地球化学过程中,对 (Sb) 同位素分离机制的了解很少,这限制了其作为环境标记物的使用.
- 由于强烈的吸附,铁 (氧化) 氧化物是Sb迁移的关键,但Sb对这些矿物质的同位素行为仍然不清楚.
研究的目的:
- 为了研究吸附机制和Sb同位素分离在铁酸盐,酸盐和血酸盐上.
- 阐明矿物学和表面复合在Sb同位素分离中的作用.
主要方法:
- 扩展的X射线吸收细结构 (EXAFS) 光谱法用于研究Fe (oxyhydr) 氧化物上的Sb吸附.
- 在不同的条件下,量化Sb同位素分离 (Δ123S水性吸附) 的量化.
主要成果:
- 观察到Sb物种与Fe (oxyhydr) oxides的内部球体复合,独立于pH值和表面覆盖.
- 较轻的Sb同位素优先通过同位素平衡分化对Fe (oxyhydr) 氧化物进行丰富.
- 由于表面复合较弱,与铁酸盐相比,在血和哥酸盐上发生了较大的Sb同位素分离.
结论:
- 吸附机制和Sb同位素在Fe (oxyhydr) 氧化物上的分化是pH值和表面覆盖面独立的.
- 矿物质结构影响Sb同位素分离,对环境追踪有影响.
- 这项研究为在源和过程追踪中应用Sb同位素提供了基础.
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