合成和改善了SnF的光发光
Jisheng Xu1, Haixia Wu1, Xinye Lu1
1School of Materials Science and Engineering, Hanshan Normal University, Chaozhou 521041, China.
Materials (Basel, Switzerland)
|June 10, 2023
概括
快速的热处理增强了添加的化 (CsSnCl3:Mn2+) 矿中的红色排放. 这种方法提高了光发光和热稳定性,用于先进的光学应用.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 光物理学的光学物理学
背景情况:
- 化 (CsSnCl3) 矿是光电子应用的有希望的材料.
- (Mn2+) 兴奋剂引入发光,但可能对合成和加工条件敏感.
研究的目的:
- 开发CsSnCl3:Mn2+矿的快速合成方法.
- 研究快速热处理对其光发光 (PL) 特性和热稳定性的影响.
主要方法:
- 从SnF2.2中快速合成CsSnCl3:Mn2+矿石.
- 快速热处理前后的光发光的特征.
- 分析发光动力学和热稳定性的分析.
主要成果:
- 纯净的CsSnCl3:Mn2+在~450nm (蓝色) 和~640nm (红色) 呈现双PL峰值.
- 快速热处理显著减少了蓝色排放,几乎使红色排放强度翻了一番.
- 用添加剂的样本在后处理后显示了增强的热稳定性.
结论:
- 快速的热处理通过增强激发状态密度和能量转移来优化CsSnCl3:Mn2+发光.
- 该过程减少了非辐射重组,从而改善了红色发射和热稳定性.
- 这些发现为控制和增强稀土化CsSnCl3排放提供了途径.
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