在广泛的温度范围内,哈夫纳酸的结构,抗铁电和储能性能
Vidhi Chauhan1, Bi-Xia Wang1, Zuo-Guang Ye1
1Department of Chemistry and 4D Labs, Simon Fraser University, Burnaby, BC V5A 1S6, Canada.
Materials (Basel, Switzerland)
|June 10, 2023
概括
甲酸盐 (PbHfO3) 显示出出色的抗铁电 (AFE) 性能,用于储能. 这项研究揭示了在室温和中间阶段的最佳性能,证明了其在广泛温度应用中的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 储能 储能 储能 储能 储能 储能
背景情况:
- 甲酸盐 (PbHfO3) 是一种有前途的抗铁电 (AFE) 材料,用于储能应用.
- 它的室温 (RT) 储能性能及其高温中间阶段 (IM) 的特征仍然未得到充分探索.
研究的目的:
- 研究PbHfO3陶在室温和其中间阶段的储能性能.
- 描述PbHfO3在一系列温度范围内的结构和电气性能.
主要方法:
- 高质量的PbHfO3陶的固态合成途径.
- 高温X射线衍射 (HT-XRD) 用于结构分析.
- 在RT和高温下进行极化电场 (P-E) 测量.
主要成果:
- 确定了PbHfO3的IM为正方体 (Imma空间组) 与反平行Pb2+离子对齐.
- 在RT实现了2.7J/cm3的最佳可回收能量存储密度 (Wrec),比报告数据增加了286%,效率为65%.
- 在190°C观察到0.7 J/cm3的Wrec,效率为89%.
结论:
- 从室温到200°C,PbHfO3作为原型的AFE材料起作用.
- 该材料在广泛的温度谱中显示出高性能储能的巨大潜力.
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