类似花朵的尿素-甲树脂微球用于吸附银离子
Yuhan Li1, Xiaoli Wang2, Jing Xia3
1Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China.
Polymers
|June 10, 2023
概括
研究人员开发了类似花朵的硫尿素-甲微球 (FTFM),以增强银离子吸附. 这些新型的微球显著增加了从回收材料中提取银的回收率,为工业应用提供了具有成本效益的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 银的回收利用至关重要,酸盐树脂是银离子吸附的关键.
- 提高树脂的银离子吸附能力是一个持续的研究目标.
研究的目的:
- 为高效的银离子吸附合成类似花朵的硫尿素-甲微球 (FTFM).
- 研究合成参数对FTFM形态和吸附性能的影响.
主要方法:
- 一步酸催化反应以制备具有控制形态的FTFM.
- 特定表面积和微观结构的表征.
- 使用动力学和异热学研究评估银离子吸附能力.
主要成果:
- 与对照微球相比,FTFM的特定表面积显著更高 (18.98 ± 0.949 m2/g).
- 最大的银离子吸附能力达到18.17 ± 1.28 mmol/g,是对照组的13.8倍.
- FTFM表现出极好的吸附效率和容量,具有快速的动力学.
结论:
- 类似花朵的尿素-甲微球在银离子吸附方面表现出卓越的性能.
- 易于制备和高效率使FTFM成为工业银回收的有希望的材料.
- 进一步的研究可以优化FTFM用于贵金属回收的大规模应用.
更多相关视频
12:47Tangential Flow Ultrafiltration: A “Green” Method for the Size Selection and Concentration of Colloidal Silver Nanoparticles
Published on: October 4, 2012
18.0K
08:19Synthesis, Characterization, and Functionalization of Hybrid Au/CdS and Au/ZnS Core/Shell Nanoparticles
Published on: March 2, 2016
18.3K
相关概念视频
Colloidal precipitates
629
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
629
Formation of Complex Ions
23.8K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.8K
