含结构的多 (DL-乳化物) 的合成和表征
Chung-Fu Yu1, Syang-Peng Rwei1,2, Shung-Jim Yang3
1Institute of Organic and Polymeric Materials, Research, National Taipei University of Technology, Taipei 106344, Taiwan.
Polymers
|June 10, 2023
概括
这项研究合成了一种新型的Poly ((DL-乳化物) 聚合物 (DL-BPF) 与双二和烯酸盐组. 由此产生的光交联聚合物在光学上透明,热稳定,生物兼容,显示了先进光学应用的潜力.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 生物材料是一种生物材料.
背景情况:
- 双二 (BPF) 衍生物具有独特的结构性质.
- 聚 ((DL-乳化物) 是一种具有已确定的生物相容性的可生物降解聚合物.
- 烯酸盐的功能组使材料制造的光交联成为可能.
研究的目的:
- 合成一种新型的Poly ((DL-乳酸) 共聚合物,其中包含双二和烯酸功能 (DL-BPF).
- 描述合成的聚合物及其光交联网络.
- 评估交联材料的光学,热和细胞毒性质.
主要方法:
- 由BPF基组启动的DL-乳化物的环开聚合.
- 使用NMR (H,C) 和凝透色谱的聚合物表征.
- 使用Omnirad 1173进行DL-BPF的光交联,然后进行表征 (凝含量,折射率,DSC,TGA,细胞毒性测试).
主要成果:
- 成功合成DL-BPF聚合物与双二和烯酸盐组.
- 形成一个光学透明的光交联聚合物.
- 达到1.5276的最大折射率,6.1°C的玻璃过渡温度和>83%的细胞活力.
结论:
- 新型DL-BPF共聚合物可以通过光学交叉连接成为光学透明,热稳定和生物相容的材料.
- 这种材料显示出在先进光学设备和生物医学领域的应用潜力.
- 双二,聚DL-乳酸和烯酸盐组的组合产生了有前途的材料特性.
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