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相关概念视频

Bonding in Metals02:32

Bonding in Metals

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Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

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An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
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Theory of Metallic Conduction01:17

Theory of Metallic Conduction

1.4K
The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
1.4K
Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
13.6K
Metal-Semiconductor Junctions01:24

Metal-Semiconductor Junctions

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The contact of metal and semiconductor can lead to the formation of a junction with either Schottky or Ohmic behavior.
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The...
395
Biasing of Metal-Semiconductor Junctions01:27

Biasing of Metal-Semiconductor Junctions

288
Biasing metal-semiconductor junctions involves applying a voltage across the junction. Specifically, the metal is connected to a voltage source, while the semiconductor is grounded. This technique is essential for controlling the direction and magnitude of current flow in electronic devices, including diodes, transistors, and photovoltaic cells.
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
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Iron Nanowire Fabrication by Nano-Porous Anodized Aluminum and its Characterization
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合金核心-外纳米线异构结构中的形状和组成演变,由亚原子扩散诱导.

Delong Han1, Wenlei Tang2, Naizhang Sun2

  • 1Shandong Computer Science Center (National Supercomputer Center in Jinan), Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China.

Nanomaterials (Basel, Switzerland)
|June 10, 2023
PubMed
概括

原子扩散显著影响合金核心外纳米线的形状和组成,这对于光电子设备至关重要. 了解这些运动过程是控制纳米线的生长和性能的关键.

关键词:
合金组成合金组成核心外异构结构 核心外异构结构增长模式的增长模式.形态学 形态学 形态学纳米线纳米线的使用方法

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科学领域:

  • 材料科学 材料科学 材料科学
  • 纳米技术纳米技术
  • 计算物理 计算物理

背景情况:

  • 核心外纳米线异构结构是先进光电子设备的重要组成部分.
  • 控制这些异构结构的形态和组成对于设备的性能至关重要.

研究的目的:

  • 开发和利用合金核心外纳米线异构结构的增长模型.
  • 为了研究 adatom 扩散在纳米线生长过程中的形状和组成演变的影响.

主要方法:

  • 使用有限元法,数值解决短暂扩散方程.
  • 纳入的扩散,吸附,脱附,和纳入动力学的 adatoms.
  • 模拟移动边界以考虑侧墙增长.

主要成果:

  • 阿达原子扩散导致位置依赖和时间依赖的阿达原子度.
  • 纳米线外形态,包括厚度分布和接触角度,强烈依赖流体冲击角度.
  • 在纳米线和外生长方向上,由于 adatom 扩散,组成配置是不均的.

结论:

  • 动力模型成功阐明了原子扩散在合金核心外纳米线塑造中的作用.
  • 系统的调查揭示了扩散长度,自然寿命和成分比对进化的影响.
  • 该模型为成长的合金组-IV和组III-V核心纳米线异构结构提供了洞察力.