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Updated: Jul 27, 2025

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揭示有机硫源对合成MoS2阶段和电催化进化性能的影响

Jiaqi Liu1, Jing Wang2, Baoqiang Wei2

  • 1Yan'an Quality and Technical Inspection Institute, Yan'an 716000, China.

Inorganic chemistry
|June 10, 2023
PubMed
概括

研究人员发现,有机硫源的分解温度控制了二硫化 (MoS) 的相位. 较低的分解温度产生金属MoS,提高其演化反应 (HER) 的性能.

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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Sulfur is an essential element in biological systems, contributing to synthesizing key biomolecules, including amino acids such as cysteine and methionine, and cofactors such as coenzyme A and biotin. Microorganisms primarily assimilate sulfur as sulfate (SO₄²⁻) from the environment, which must undergo a series of biochemical transformations before it can be incorporated into cellular components. As sulfate is highly oxidized, it must undergo assimilatory sulfate reduction to...
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