泡过程对PET-PEN共聚物的燃烧行为的影响
Dong Hyeon Kim1, Byeong Jun Lee1, Byung Kyu Park2
1School of Mechanical Engineering, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Korea.
ACS omega
|June 12, 2023
概括
两步泡比一步方法更好地控制PET-PEN共聚合物泡形态. 这会影响机械性能和燃烧行为,两步泡在燃烧后的残留物显著减少.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 泡制造业 泡制造业 在
背景情况:
- 制造工艺显著影响泡的性能.
- 一步泡很简单,但与两步方法相比,它提供了较差的形态控制.
研究的目的:
- 通过一阶段和两阶段泡制成的PET-PEN共聚合物之间的热和机械性能,特别是燃烧行为方面的差异.
- 分析泡温度对材料性能的影响.
主要方法:
- 对PET-PEN共聚合物的一步和两步泡工艺的实验比较.
- 评估热性质 (热膨胀系数) 和机械性质 (断裂应力).
- 分析燃烧行为,包括质量燃烧速度和残留物形成.
主要成果:
- 在单步工艺中,泡温度的提高导致了更脆弱的PET-PEN共聚物.
- 在高温下发泡的一级PET-PEN泡显著降低了断裂压力.
- 燃烧后,两步泡PET-PEN的残留量显著减少 (1%),与单步 (41-55%) 相比.
- 热膨胀系数在一个阶段的PET-PEN中相比于两个阶段的PET-PEN要低得多.
结论:
- 两步泡为PET-PEN共聚合物泡形态提供了更好的控制,从而提高了机械完整性和明显的燃烧特性.
- 制造方法极大地影响PET-PEN泡的热性能和机械性能,特别是燃烧过程中的行为.
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