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石墨烯氧化物稳定皮克林乳液的风湿学
Shu-Ming Cui1,2, Saud Hashmi3, Wen-Qiang Li1
1College of Materials Science and Engineering, Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, Nanshan District Key Laboratory for Biopolymers and Safety Evaluation, Shenzhen University, Shenzhen 518055, P. R. China. yanfeihuang@szu.edu.cn.
Soft matter
|June 12, 2023
概括
石墨烯氧化物 (GO) 和二甲基二甲基化物 (DDAB) 稳定了用于3D打印的皮克林乳膜. 它们的结构和界面干扰行为被使用显微镜,介电光谱和风学阐明.
科学领域:
- 材料科学 材料科学 材料科学
- 合体和表面化学
背景情况:
- 皮克林乳化剂是多功能系统,在先进材料中具有应用.
- 石墨烯氧化物 (GO) 和像二甲基二甲基化物 (DDAB) 这样的表面活性剂是稳定乳化剂的关键组成部分.
- 了解结构-属性关系对于优化它们的性能至关重要,特别是在3D打印中.
研究的目的:
- 为了阐明由GO和DDAB稳定Pickering乳化物的结构.
- 为了研究这些乳化剂在不同条件下的界面干扰行为.
- 为了将结构性质与3D打印应用中的质性行为相关联.
主要方法:
- 显微镜 (切割前后) 用于结构分析.
- 宽带介电光谱检测接口动力学.
- 风病学 (线性和非线性疗法) 用于描述机械性能.
- 在剪切过程中对正常力进行分析.
主要成果:
- 增加的DDAB和GO含量系统地提高了模量和粘度.
- 较高的度降低了非线性风湿疗法的极限.
- 观察到复杂的正常力变化,包括低GO含量时的负力和高GO含量时的正力.
- 界面阻塞是由滴滴变形,阻塞和恢复动态解释的.
结论:
- 这项研究提供了对皮克林乳液结构和界面干扰的全面了解.
- 这些发现为优化3D打印油墨的乳配方提供了洞察力.
- 在GO,DDAB和油相之间的相互作用决定了质性和可打印性.
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