协调的抗原子在碳基质上作为有效的活性站点来增强/离子储存
Yong Tong1, Yuanji Wu1, Xi Liu1
1Department of Materials Science and Engineering, College of Chemistry and Materials Science, Jinan University, Guangzhou 510632, PR China.
Journal of colloid and interface science
|June 12, 2023
概括
在离子和离子电池中,用反添加的硬碳阳极表现出增强的性能. Sb-N协调站点改善了下一代能源设备的离子存储能力和动力学.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 碳基阳极材料对于金属离子电池至关重要.
- 提高电化学性能需要微纳米结构设计和原子兴奋剂等策略.
研究的目的:
- 准备和研究用于增强的金属离子电池阳极的反添加硬碳 (SbNC) 材料.
- 探索Sb兴奋剂和协调在碳矩阵上的协同效应.
主要方法:
- 合成反添加添加碳 (SbNC) 材料.
- 在离子和离子半电池中进行电化学表征.
主要成果:
- SbNC 阳极表现出高速率容量 (109 mAh g−1 在 20 A g−1 在 Na-ion 电池中) 和出色的循环稳定性 (254 mAh g−1 在 1 A g−1 在 2000 个循环后).
- 在K离子电池中,SbNC阳极在0.1 A g−1时达到382 mAh g−1的初始充电容量,在5 A g−1.1时达到152 mAh g−1的速率容量.
- 与简单的兴奋剂相比,Sb-N协调部位显著提高了吸附能力,离子扩散和电化学反应动力学.
结论:
- 抗兴奋剂,特别是Sb-N协调,是改善金属离子电池硬碳阳极的有效策略.
- 开发的SbNC材料为先进的离子和离子储能应用提供了有前途的电化学性能.
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