在低温CO氧化过程中,Sn-doped Pt/TiO2上的CO吸附引发的逆氧溢出
Jianjun Chen1, Shangchao Xiong2, Haiyan Liu1
1State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, PR China.
Nature communications
|June 13, 2023
概括
这项研究激活了使用兴奋剂的/二氧化催化剂的逆氧溢出. 这种增强显著增加了低温下一氧化碳的氧化.
科学领域:
- 催化剂是一种催化剂.
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
背景情况:
- 氧气溢出对氧化还原反应至关重要,但其机制,特别是反向氧气溢出,仍然不太了解.
- 在氧化物上支的被广泛用于催化,但优化其活性,特别是在低温下,是一个持续的挑战.
研究的目的:
- 研究Pt/TiO2催化剂中低温逆氧溢出机制.
- 通过 (Sn) 的注来增强Pt/TiO2用于CO氧化的催化活性.
主要方法:
- (Sn) 化为TiO2.2,使 (Sn) 成为TiO2.
- 近环境压力X射线光电子光谱学 (NAP-XPS).
- 在现场的拉曼和红外 (红外) 光谱仪.
- 一开始的分子动力学 (AIMD) 模拟.
主要成果:
- 在Pt/TiO2催化剂中,Sn兴奋剂激活低温 (<100°C) 逆转氧气溢出.
- 反向氧溢出是由Pt2+位点的CO吸附引发的,导致Ti-O-Sn键裂变和Pt4+形成.
- 来自Ti-O-Sn部分的氧气优先形成具有催化活性的Pt-O物种.
结论:
- 这项研究阐明了CO引发的反向氧气溢出界面化学.
- 兴奋剂提供了一种可行的策略,可以增强低温CO氧化,而不是/催化剂.
- 这些发现为设计各种反应的先进/催化剂提供了洞察力.
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