带有 permanganate 的反应性氧化剂对电凝中的花的影响:转化和界面相互作用
Jing Zhao1, Jiaxuan Yang1, Liu Yang1
1State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China.
Environmental science & technology
|June 14, 2023
概括
含有酸的电凝/超过 (PECUF) 过程迅速启动,形成有效去除自然有机物 (NOM) 的花. 该系统优化了超过性能,减少了污染,改善了水的再利用.
科学领域:
- 环境工程 环境工程
- 水处理技术水处理技术
- 合体和表面化学
背景情况:
- 废水量不断增加和复杂的水再利用挑战需要先进的处理解决方案.
- 电凝/超 (ECUF) 过程显示出有希望的结果,但像酸含有ECUF (PECUF) 这样的增强系统中的机制尚未完全理解.
- 澄清这些机制对于优化分散式水处理系统至关重要.
研究的目的:
- 系统地研究PECUF过程中的花形成,与有机物相互作用和界面特性.
- 阐明 permanganate 在 PECUF 系统性能中的作用.
- 了解PECUF优化超 (UF) 性能背后的原理.
主要方法:
- 在PECUF过程中系统地探索花,它们的形成,对自然有机物 (NOM) 的反应和接口特征.
- 分析了酸通过MnO2形成的作用及其对电荷转移的影响.
- 应用扩展的德贾古因-兰道-维维-奥弗比克 (DLVO) 理论来分析UF性能优化.
主要成果:
- 酸通过形成MnO2加速凝血的启动,抑制吸附Fe (II) 和固态Fe (III) 之间的电荷转移.
- 对NOM的反应取决于时间和颗粒大小,最佳吸附时间为5-20分钟,除去时间为20-30分钟.
- PECUF模块降低了蛋糕层的阻力,保持了初始流量 (15%的下降),并增强了对长期防物的颗粒排斥.
结论:
- PECUF过程通过优化特征,证明了高效的启动和NOM移除.
- 扩展的DLVO理论解释了PECUF如何通过修改合溶液和增加粒子间排斥来提高UF性能.
- 研究结果为设计和控制分散水处理中按需组装模块提供了关键的见解.
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